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At peek times, it has a ratio of approximately one girl in 8 connections, though this gets much worse the rest of the day (1 in 20 ).
It works best in the evenings (US eastern Standard time to Pacific time), and at weekends.
"We have been concerned about chatrooms for a while and reached a stage where we were no longer prepared to put up with inappropriate communication," he said.
The only chat service available to MSN users in the UK will be the free instant messaging service, MSN Messenger, which is not so open and gives people more control over who they talk to.
Children's charities welcomed the move as "momentous" and said they saw it as a big step towards protecting young web users, but some have criticised the decision.
Abusive contact Internet service provider Lycos has branded the action as "irresponsible" and fear children will move to other unmoderated chatrooms on the net.
"We have seen cases where under-16s have been approached by people pretending to be same age, but who are grown adults trying to solicit young people for abusive contact," Mr Whittingham explained.
Many have been "mining" rooms for data, finding out users' e-mail addresses to build spam lists. MSN has acknowledged that some chatters will not be happy about the move.
"We regret responsible users will be affected by this move, but we looked at this very carefully and on balance to safeguard customer interests," said Mr Whittingham.
This means never giving out personal information online, and never arranging to see someone they have met online in the real world.
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